At Williams since 2002
Lab: Morley Science Laboratory, Room 157 (413) 597-3700
Areas of ExpertiseSingle Molecule Spectroscopy of Dynamic Heterogeneities From windows to synthetic polymers, from fiber optics to sugar coatings on corn flakes, glasses are ubiquitous in our daily lives. With physical properties of a solid and microscopic structure of a liquid, glasses are neither; they evolve slowly over time. In the past few years the focus of research on these materials has gradually shifted from a macroscopic description of properties to their analysis on a molecular scale. One especially promising result explains their unusual properties as a consequence of a strong dependence of a molecule's dynamics on the structure of its environment, a correlation often called “dynamic heterogeneity.” Our research pushes this molecular description of glass dynamics to its extreme: using single molecule spectroscopy to investigate glasses experimentally one molecule at a time along with molecular dynamics simulations on fast computers to study the theory of the glass transition at the same level of detail.
Scholarship/Creative WorkSelected Publications
- "Heterogeneous Dynamics and Dynamic Heterogeneities at the Glass Transition Probed with Single Molecule Spectroscopy," A.N. Adhikari, N.A. Capurso, D. Bingemann, , Journal of Chemical Physics, 127 (8), 114508 (2007).
- "Decoupled Dynamics and Quasi-Logarithmic Relaxation in the Polymer-Plasticizer System Poly(Methyl Methacrylate)/Tri-m-Cresyl Phosphate Studied with 2D NMR," D. Bingemann, N. Wirth, J. Gmeiner, E. A. Rössler, Macromolecules, 40 (15), 5379-5388 (2007). DOI: 10.1021/ma070519g.
- "Analysis of "blinking" or "hopping" single molecule signals with a limited number of transitions," D. Bingemann, Chemical Physics Letters 433, 234-238 (2006).
- "Vibrational Relaxation of CH2I2 in solution: Ecitation Level Dependence," C. G. Elles, D. Bingemann, M. M. Heckscher, F. Fleming Crim, J. Chem. Phys. 118, 5587 (2003).
- "Relaxation of the C-H stretching fundamental vibrations of CHI3, CH2I2, CH3I in solution," M.M. Heckscher L. Sheps, D. Bingemann, F. Fleming Crim, J. Chem. Phys. 117, 8917 (2002).
- "CH2I2: Fundamental Vibrational Relaxation in Solution Studied by Transient Electronic Absorption", C. M. Cheatum, M. M. Heckscher, D. Bingemann, F. F. Crim, J. Chem. Phys., 115, 7086 (2001).
- "Transient electronic absorption of vibrationally excited CH2I2: Watching energy flow in solution," D. Bingemann, A. M. King, and F. F. Crim, J. Chem. Phys. 113, 5018 (2000).
- "Time-resolved vibrationally mediated photodissociation of HNO3: Watching vibrational energy flow," D. Bingemann, M. P. Gorman, A. M. King, and F. F. Crim, J. Chem. Phys. 107, 661 (1997).
- "Femtosecond Solvation Dynamics Determining the Band Shape of Stimulated-Emission from a Polar Styryl Dye," D. Bingemann and N. P. Ernsting, J. Chem. Phys. 102, 2691 (1995).
- "A New Cell Design for Off-Axis Amplification of Ultrashort Dye-Lasers Which Uses Total Internal-Reflection," T. Bultmann, D. Bingemann, N. P. Ernsting, D. Schwarzer, and L. Nikowa, Rev. Sci. Instrum. 66, 4393 (1995).
Previous Courses Taught
- CHEM 153: Concepts of Chemistry: Advanced Section
- CHEM 155: Concepts of Chemistry: Advanced Section
- CHEM 366: Physical Chemistry: Thermodynamics
- CHEM 368T: Quantum Chemistry and Molecular Spectroscopy
- ENVI 102: Introduction to Environmental Scienes
- CHEM 11: Science for Kids (Winter Study Program)
- Christian Bonn '09
- Rachel Allen '08
- Aashish Adhikari '07
- James Brittin '06
- Noah Capurso '05
- John Harris '05
- Gerry Lindo '04
- Alison Peet '03
Summer Research Students
- 2007: Elizabeth Upton ’08, Avalon Gulley ’09 (in Environmental Sciences with Jay Thoman and David Richardson)
- 2006: Aashish Adhikari ’07,Johnathan Dahlberg ‘09
- 2005: Ben Rudick ’08, Ashleigh Theberge ’06
- 2004: Geoff O’Donoghue ’06, Nat Erb-Satullo (Swarthmore ‘07), Noah Capurso ’05
- 2003: John Harris ’05, Noah Capurso ’05, Gerry Lindo ‘04